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Hydrogeology and Environmental Studies

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Subsurface Remediation and Contaminant Transport
The Groundwater and Subsurface Remediation graduate subprogram spans several departments and disciplines at Michigan Tech. Groundwater-related coursework and research address issues of contaminant fate and transport as well as engineering aspects of subsurface remediation and water quality protection. Research activities range from basic-level, theoretical laboratory and mathematical modeling studies of contaminant transport mechanisms up to applied, field-scale experimental and modeling studies of contaminant remediation and groundwater quality protection. Current and recent research include surfactant-enhanced flushing of nonaqueous phase liquid contaminants, air sparging of volatile chemicals at field sites in Utah and Delaware, saltwater intrusion in aquifers in Mexico, optimization of grounwater pump-and-treat, to name a few.

Research Grants
Multi-Scale Investigation of Mass Transfer Limitations in Surfactant- Enhanced Aquifer Remediation, Alex Mayer, Environmental Protection Agency, $474,000, 11/96 to 10/00 (in cooperation with University of Texas).

Multi-Objective Decision-Making for Environmental Remediation, Alex Mayer, Environmental Protection Agency, $292,000, 9/98 to 8/01 (in cooperation with Northern Michigan University).

U.S. Department of Energy, $326,271, 8/6/96 - 9/20/99, Field-scale model for air sparging performance assessment and design, N. J. Hutzler, J. S. Gierke, G. L. Hein, and R. W. Falta (Clemson University).

U.S. Environmental Protection Agency, $460,339, 8/1/97 - 8/31/00, Design guidance for air sparging of DNAPLs in unconsolidated geologic environments, J. S. Gierke, N. J. Hutzler, and D. L. Perram.
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Basin/Regional Scale Hydrogeology/Hydrology
First, we are interested in assessing the role of fault systems in controlling regional groundwater flow. We are investigating a 14-km section of the San Andreas fault in the vicinity of Desert Hot Springs, California. This fault section behaves as a barrier and produces head drops of 50-70 meters across the fault. We have gathered field data and produced a calibrated groundwater model, resulting in estimates of the fault conductance and flow across the fault. This work is conducted in cooperation with local water agencies and colleagues at the California State University at Bakersfield. Future work will focus on gathering additional field data (e.g. in situ measurements of the fault hydraulic conductivity) to improve the model.

Our second area of research concerns saltwater intrusion into an aquifer in Sonora, Mexico. Saltwater has intruded as far as 10 km from the coast of the Sea of Cortez into the local groundwater aquifer, which is heavily utilized for irrigation. Colleagues at the University of Sonora, Hermosillo, Mexico, have been collecting hydrogeologic information to assist in the development of a mathematical model of the local groundwater system. The resulting model will be capable of predicting the position of the saltwater-freshwater front as a function of time. The eventual goal of the modeling efforts is to develop sustainable policies for managing the water resources for the area. More generally, we are interested in identifying and quantifying the processes responsible for diffusing saltwater-freshwater fronts, such as the relationship between recharge and mixing due to heterogeneity.

Research Grants
A Mathematical Modeling Approach to Determine the Advance of Saline Intrusion in the Guaymas Valley, Sonora, Mexico, Alex Mayer, Consejo Nacional de Ciencia y Tecnologia (Mexico), $38,000, 5/97 to 10/99 (in cooperation with University of Sonora, Mexico)

National Science Foundation, $103513, 1/1/95 to 12/31/99, Aquifer Heterogeneity Estimation using Ground Penetrating Radar, C. T. Young

National Science Foundation, $10000. 1/1/96 to 12/31/99, Research Experience for Undergraduates Supplement to Aquifer Heterogeneity Estimation using Ground Penetrating Radar, C. T. Young.
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Environmental/Aqueous Geochemistry
We have been monitoring selected small watersheds, and comparing hydrologic and chemical outputs to those of large watersheds which also drain into Lake Superior, to help develop geochemical cycling models of the Lake Superior basin. With a transfer student from Germany, we are studying the mineralogy and weathering characteristics of local mine waste deposits (stamp sands), to help determine if they pose a potential environ mental hazard.

Research Grants
Hydrologic and Geochemical Monitoring and Analysis of Three Watersheds Draining Michigan's Keweenaw Peninsula into Lake Superior. $5,000, from 3/1/99 to 3/1/00; G. Bluth, R.R. Cookman.
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Near Surface Geophysics
Near surface geophysics at MTU consists of applying magnetic, gravity, electromagnetic, radar, electrical and seismic methods to study the upper 1000, 100, 10 or upper one meter of the Earth. The applications are enormous but we concentrate on environmental applications such as locating buried waste, contamination plumes, looking at soil and rock structure to estimate where groundwater will flow, determining the depth to bedrock for building foundations or highways, and assisting archaeologists to locate buried cultural artifacts. We have modern equipment for all these methods, and have powerful computer programs for two and three dimensional display and interpretation of the data. We have recently purchased a magnetometer which can acquire data as it is moved across the ground at a brisk walk, and are trying to get support to upgrade other equipment. We have field sites for undergraduate teaching and undergraduate and graduate research, and we encourage students to pursue these topics on their own. We have joint projects with civil and environmental engineering and with industrial archaeology.
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Faculty Information

    Mayer, Alex PE Associate Professor of Geological and Environmental Engineering
    Ph.D., University of North Carolina - Chapel Hill
    Multi-phase fluid flow and contaminant transport in porous media, experimental and computational hydrogeology
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    Debasmita Misra     Research Assistant Professor of Geology
    Ph.D., University of Minnesota
    Field scale characterization of flow and transport in soils, aquifers and petroleum reservoirs
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    James R. Wood Jr.     Professor of Geology
    Ph.D., Johns Hopkins University
    Geochemistry, environmental geology, diagenesis, petroleum geology
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    Charles T. Young, PE     Associate Professor of Geophysical Engineering
    Ph.D., University of Wisconsin--Madison
    Exploration geophysics, electrical and electromagnetic geophysics, geophysical signal analysis, ground-penetrating radar, environmental geophysics
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    Gregg Bluth     Associate Professor of Geology
    Ph.D., Pennsylvania State University
    Earth/atmosphere interactions, remote sensing of volcanic emissions, watershed geochemistry
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    John S. Gierke     Associate Professor of Geology
    Ph.D., Michigan Technological University
    field performance of air sparging for removing volatile organic chemicals from ground water, volatile organic vapor transport in unsaturated soils, sulfur dioxide interactions with volcanic ash
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Courses

    GE4400 - Near Surface Geophysics I

    GE4410 - Near Surface Geophysics II

    GE4800 - Groundwater Engrg.

    GE4810 - Groundwater Site Investigation

    GE4820 - Subsurface Remediation

    GE4900 - Geological Engrg. Design Project I

    GE4910 - Geological Engrg. Design Project II

    GE5800 - Mathematical Models in Earth Systems

    GE5810 - Flow Transport in Subsurface Systems

    GE5820 - Fundamentals of Subsurface Remediation

    GE5825 - Subsurface Remediation Lab
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Research/Publications

    Abulaban, A., J.L. Nieber, and D. Misra, 1998: Modeling Plume Behavior for Nonlinearly Sorbing Solutes in Saturated Homogeneous Porous Media, Advances in Water Resources, Vol. 21, 487-498.

    Bluth, G.J.S. and L.R. Kump (1994) Lithologic and climatologic controls of river chemistry. Geochimica et Cosmochimica Acta, 58, 2341-2359.
    Bluth, G.J.S. and L.R. Kump (1991) Phanerozoic paleogeology: A new dimension to geochemical cycling models. American Journal of Science, 291, 284-308.

    M. Cil, J.C. Reis, M.A. Miller, D. Misra, 1998: An Examination of Countercurrent Capillary Imbibition Recovery from Single Matrix Blocks and Recovery Predictions by Analytical Matrix/Fracture Transfer Functions, Paper No. 49005, Proceedings of the 1998 Annual International SPE meeting in New Orleans, LA, p.237-251.

    Gibbs, M.T., G.J.S. Bluth, P.J. Fawcett, and L.R. Kump (1999, in press) Chemical weathering over the last 250 Myr: variations due to changes in paleogeography, paleoclimate, and palogeology. American Journal of Science.

    Gierke, J.S., C.L. Wojick, and N.J. Hutzler, "Field Test of Air Sparging Coupled with Soil Vapor Extraction," Chapter 10 in Innovative Subsurface Remediation: Field Testing of Physical, Chemical, and Characterization Technologies, ACS Symposium Series 725 , edited by M.L. Brusseau, D.A., Sabatini, J.S. Gierke, and M.D. Annable, American Chemical Society, Washington, D.C., 153-166, 1999.

    Gierke, J.S., D.L. Sanders, and D.L. Perram, "Laboratory Studies of Aqueous Partitioning Tracer Tests for Measuring Nonaqueous Phase Liquid Volumes," Water Environment Research, 71(4), 465-474, 1999.
    Gierke, J.S., and S.E. Powers, "Increasing Implementation of In-Situ Treatment Technologies Through Field-Scale Performance Assessments," Water Environ. Res., 69(2), 196-205, 1997.

    Huang, C. and A.S. Mayer, "Development and Application of a Coupled-Process Parameter Inversion Model Based on Maximum Likelihood Estimation and Genetic Algorithms," Advances in Water Research, 841-853, 1999.

    Huang, C. and A.S. Mayer, "Pump-and-Treat Optimization Using Well Locations and Pumping Rates as Decision Variables," Water Resources Research, 33(5), pp. 1001-1012, 1997.

    Lemke, S., and Young, C. T, 1998, Leachate plume investigation using mise-a-la-mass resistivity, Proceedings of the Symposium on the Application of Geophysics to Engineering and Environmental Problems, March 22-25, Chicago, 839-847.

    Mayer, A.S., L. Zhong, and G. Pope, "Measurement of Mass Transfer Rates for Surfactant-Enhanced Solubilization of Nonaqueous Phase Liquids," Environmental Science & Technology, in press, 1999.

    Mayer, A.S. and R.J. Lenhard, "Recent Advances in Modeling the Flow and Transport of Nonaqueous Phase Liquids in Subsurface Systems," co-editors, Advances in Water Research, 21(2), pp. 75-181, 1998.

    Mayer, A.S. and C.T. Miller, "The Influence of Mass Transfer Characteristics and Porous Media Heterogeneity on Nonaqueous Phase Liquid Dissolution," Water Resources Research, 32(6), pp. 1551-1567, 1996.

    D. Misra, R.A. Schatzinger, M. Cil, and J. Wheeler, 1998: Assessment of Later al Variability of Geological Parameters using Modal and Geostatistical Analysis of Outcrop Analog, Paper No. 49280, Proceedings of the 1998 Annual International SPE meeting in New Orleans, LA, p. 683-695.

    Mitchell, R.J. and A.S. Mayer, "A Model for Transient-Hysteretic Flow and Solute Transport in Unsaturated Porous Media," Journal of Contaminant Hydrology, 30(3-4), pp. 243-264, 1998.

    Mitchell, R.J. and A.S. Mayer, "Significance of Transient and Hysteretic Flow in Modeling Transport in Unsaturated Porous Media," Soil Science Society of America Journal, 87(5), 555-566, 1998.

    Sloan, L.C., G.J.S. Bluth, and G.M. Filippelli (1997) A comparison of spatially-resolved and global mean reconstructions of continental denudation under ice-free and present conditions. Paleoceanography, 12, 147-160.

    L. Tomutsa, D. Misra, S. Swan and R.A. Schatzinger, 1998: A Comparative Analysis of Wavelet Based and Incomplete Layers Upscaling Models for single-phase flow simulations, Topical Report No. NIPER/BDM-0378, U.S. Department of Energy, National Petroleum Technology Office, Tulsa, OK.

    Young, C. T., 1998, Can radar predict the scale of hydraulic conductivity?, GPR'98 Seventh International Conference on Ground-Penetrating Radar, May 27-30, Lawrence, KS, 413-417.

    Young, C. T., 1998, Fractures imaged in limestone, Proceedings of the Symposium on the Application of Geophysics to Engineering and Environmental Problems, March 22-25, Chicago, 417-426.

    Young, C. T., and Doucette, J. P., 1996, Sand variability from ground penetrating radar data, Proceedings of Uncertainty, '96, Uncertainty in the Geologic Environment: from Theory to Practice, Geotechnical Special Publication No. 58, American Society of Civil Engineers, 368-382.
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